LearnChemE

First Law - Closed Systems: Screencasts

Introduces the first law for a closed system and considers cases of constant pressure and constant volume.

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Applies the first law to a closed system for an adiabatic reversible process for an ideal gas.

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Important Equations:

Energy Balance (ignoring kinetic and potential energy):

ΔU=Q+WEC+WS

where Q is the heat added to the system
WEC is the expansion/compression work (moving a piston in a cylinder)
WS is shaft work
For most processes of importance in chemical engineering, kinetic and potential energies can be ignored.

Adiabatic/reversible compression/expansion for an ideal gas:

T2T1=(P2P1)RCP

where T1 and T2 are the absolute temperatures of the gas at the initial and final states, respectively
P1 and P2 are the initial and final pressures, respectively
R is the ideal gas constant
CP is the heat capacity at constant pressure

Heat added to the system:  Q>0 
Heat removed from the system:  Q<0
Adiabatic system:  Q=0
Work added to the system:  W>0
Work removed from the system:  W<0